Acetate Exchange Mechanism on a Zr12 Oxo Hydroxo Cluster: Relevance for Reshaping Zr-Carboxylate Coordination Adaptable Networks
نویسندگان
چکیده
The acetate ligand exchange with free acetic acid in [Zr 6 O 4 (OH) (O 2 CCH 3 ) 12 ] , used as a model of crosslink migration ]-based coordination vitrimers, has been thoroughly investigated by dynamic 1 H NMR and DFT calculations.
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2023
ISSN: ['2041-6520', '2041-6539']
DOI: https://doi.org/10.1039/d3sc02204h